ADSORPTION OF Fe (III) IONS ON MODIFIED ADSORBENT: ADSORPTION ISOTHERMS

نویسندگان

چکیده

This work is devoted to the synthesis of a new type adsorbent based on maleic anhydride styrene copolymer (MAST) and N,N`-diphenylguanidine (S) its modification with 4,4'-(ethane-1,2-diylbis(azanylylidene))bis(pentane-2-one) (S+R). Adsorption study Fe (III) ions this has been carried out. Effects pH value, contact time, ionic strength initial concentration metal adsorption capacity product have studied. In course research, several isotherms kinetic models studied equilibrium data found agree well pseudo-second-order model, model can describe process. The results best fit Langmuir isotherm model. studies shown that compared (S), for which was 404.88 mg/g, reagent-modified (S+R) shows higher over Fe(III) equal 890.68 mg/g. Synthesized characterized by Scanning Electron Microscopy (SEM) Energy Dispersive X-ray Spectroscopy (EDS) Ultraviolet-visible (Uv/Vis). Temperature stability thermal analysis methods (TG, DTA, DDTA)

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Adsorption behavior of Fe(II) and Fe(III) ions on thiourea cross-linked chitosan with Fe(III) as template.

A new type of thiourea cross-linked chitosan with Fe(III) as template (TCCTS template) was synthesized. The adsorption of Fe(II) and Fe(III) on this TCCTS template was studied. The factors affecting adsorption such as pH and contact time were considered. The results showed that the optimum pH value for adsorption was pH = 5.0 and the adsorption equilibrium time was about 60 min. The adsorption ...

متن کامل

Arsenic Adsorption from Aqueous Solutions on an Fe(III)-Si Binary Oxide Adsorbent

This study investigated arsenate and arsenite adsorption on an iron(III) oxide/silica adsorbent that had a Fe/Si molar ratio of 3. Batch experiments were conducted with regard to adsorption kinetics, isotherms, pH effects and interference of phosphate and sulfate on arsenic adsorption. The adsorption of arsenite was faster than that of arsenate. The adsorption kinetics could be well described b...

متن کامل

Water adsorption isotherms of lipids.

Hydration of bilayer lipids is a fundamental property of biological membranes. The available database of lipid hydration isotherms is fitted over the entire range of water activities by using a statistical mechanical approach that is an extension of the common Brunauer-Emmett-Teller model, to include differential energies of association for water molecules beyond the first strongly bound layer....

متن کامل

Adsorption Isotherms on Fluoride Removal: Batch Techniques

The ability of cynodon dactylon based thermally activated carbon to remove fluoride from aqueous solution has been investigated. The batch adsorption studies were carried out at neutral pH as the functions of contact time, adsorbent dose, adsorbate concentration, temperature and effect of co-anions, which are commonly present in water. The rate of adsorption was rapid during initial 105 minutes...

متن کامل

Adsorption of ions on surfaces modified with brushes of polyampholytes.

We apply density functional theory to study adsorption of ions, treated in the framework of the restricted primitive model (RPM), on surfaces modified by tethered polyampholytes. The residual electrostatic contribution to the free energy functional is approximated by using the approach proposed by Wang et al. [J. Phys.: Condens. Matter 23, 175002 (2011)] for simple nonuniform RPMs systems. Our ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Azerbaj?an himiâ žurnaly

سال: 2022

ISSN: ['2522-1841', '0005-2531']

DOI: https://doi.org/10.32737/0005-2531-2022-4-33-42